%0 Journal Article %A Llewellyn, Philip L. %A Bourrelly, Sandrine %A Serre, Christian %A Vimont, Alexandre %A Daturi, Marco %A Hamon, Lomig %A Weireld, Guy De %A Chang, Jong-San %A Hong, Do-Young %A Hwang, Young Kyu %A Jhung, Sung Hwa %A Férey, Gérard %D 2008 %T High Uptakes of CO2 and CH4 in Mesoporous MetalOrganic Frameworks MIL-100 and MIL-101 %U https://acs.figshare.com/articles/journal_contribution/High_Uptakes_of_CO_sub_2_sub_and_CH_sub_4_sub_in_Mesoporous_Metal_Organic_Frameworks_MIL_100_and_MIL_101/2927881 %R 10.1021/la800227x.s001 %2 https://ndownloader.figshare.com/files/4626376 %K CH 4. Characterization %K MIL %K cm %K FTIR %K 3STP %K CO 2 %K MOF %X Mesoporous MOFs MIL-100 and MIL-101 adsorb huge amounts of CO2 and CH4. Characterization was performed using both manometry and gravimetry in different laboratories for isotherms coupled with microcalorimetry and FTIR to specify the gassolid interactions. In particular, the uptake of carbon dioxide in MIL-101 has been shown to occur with a record capacity of 40 mmol g−1 or 390 cm3STP cm−3 at 5 MPa and 303 K. %I ACS Publications