Molecular Tectonics: Control of Reversible Water Release in Porous Charge-Assisted H-Bonded Networks Pierre Dechambenoit Sylvie Ferlay Nathalie Kyritsakas Mir Wais Hosseini 10.1021/ja806916t.s002 https://acs.figshare.com/articles/dataset/Molecular_Tectonics_Control_of_Reversible_Water_Release_in_Porous_Charge_Assisted_H_Bonded_Networks/2892049 The combinations of bisamidium dicationic tectons <b>1</b>-2H<sup>+</sup> and <b>2</b>-2H<sup>+</sup> bearing two OH groups as additional H-bond donor/acceptor sites with [M(CN)<sub>6</sub>]<sup>3−</sup><sub>2</sub> (M = Fe, Co, Cr) anions lead to the formation of robust porous crystals (decomposition temperature in the range of 240−300 °C) offering channels occupied by water molecules. The release and uptake of solvent molecules takes place through a reversible single crystal-to-single crystal transformation. Importantly, the temperature of dehydration can be increased by <i>ca</i> 40 °C through the decoration of the channels by introduction of OH groups on the backbone of the organic tecton. 2008-12-17 00:00:00 site Importantly decoration Molecular bisamidium tecton Reversible Water Release decomposition Fe donor transformation molecule combination anion formation Porou Cr dicationic Co Tectonic uptake dehydration introduction crystal offering NetworksThe release OH groups