10.1021/ol802842m.s002
Béatrice Legouin
Béatrice
Legouin
Philippe Uriac
Philippe
Uriac
Sophie Tomasi
Sophie
Tomasi
Loïc Toupet
Loïc
Toupet
Arnaud Bondon
Arnaud
Bondon
Pierre van de Weghe
Pierre
van de Weghe
Novel Chiral Molecular Tweezer from (+)-Usnic Acid
American Chemical Society
2009
spacer
Usnic
pincer
usnic acid units
ability
tweezer
molecule
Novel Chiral Molecular Tweezer
chiral
trinitrofluorenone
bind
interaction
TNF
2009-02-05 00:00:00
Dataset
https://acs.figshare.com/articles/dataset/Novel_Chiral_Molecular_Tweezer_from_Usnic_Acid/2881000
A new chiral molecular tweezer was synthesized with (1<i>R</i>,2<i>R</i>)-1,2-diaminocyclohexane as spacer and two molecules of (+)-usnic acid as pincers. The ability of this molecular tweezer to bind 2,4,7-trinitrofluorenone was studied. A charge-transfer complex was formed in which TNF was sandwiched between the two usnic acid units with π−π-stacked aromatic interactions.