Silver-Mediated Allylic Disulfide Rearrangement for Conjugation of Thiols in Protic Media David Crich Venkataraman Subramanian Maheswaran Karatholuvhu 10.1021/jo902012m.s001 https://acs.figshare.com/articles/journal_contribution/Silver_Mediated_Allylic_Disulfide_Rearrangement_for_Conjugation_of_Thiols_in_Protic_Media/2805430 Alkyl and aryl allyl disulfides are induced to undergo the desulfurative allylic rearrangement by silver nitrate in protic solvents at room temperature, thereby removing the necessity for the use of phosphines as thiophilic reagents. The silver-mediated reaction functions at ambient temperature in protic solvents and in the absence of protecting groups 2009-12-18 00:00:00 Allylic Conjugation thiophilic ambient Disulfide Thiol aryl allyl disulfides absence phosphine function nitrate necessity Rearrangement protic solvents reagent Protic desulfurative allylic rearrangement MediaAlkyl