10.1021/ol902956y.s002
Rong Zhou
Rong
Zhou
Chunzhang Wang
Chunzhang
Wang
Haibin Song
Haibin
Song
Zhengjie He
Zhengjie
He
Wittig Olefination between Phosphine, Aldehyde, and Allylic Carbonate: A General Method for Stereoselective Synthesis of Trisubstituted 1,3-Dienes with Highly Variable Substituents
American Chemical Society
2010
General Method
diene
Stereoselective Synthesis
Aldehyde
Phosphine
Variable Substituents
Trisubstituted
method exhibits
olefination
Allylic Carbonate
aldehyde
phosphine
variability
material
trisubstituted
efficiency
stereoselectivity
substituent
allylic carbonates
Diene
Wittig Olefination
synthesis
2010-03-05 00:00:00
Dataset
https://acs.figshare.com/articles/dataset/Wittig_Olefination_between_Phosphine_Aldehyde_and_Allylic_Carbonate_A_General_Method_for_Stereoselective_Synthesis_of_Trisubstituted_1_3_Dienes_with_Highly_Variable_Substituents/2786890
A clean and salt-free Wittig olefination between phosphines, aldehydes, and allylic carbonates is described. It represents a general method for convenient and efficient synthesis of 1,2,4-trisubstituted 1,3-dienes from readily available starting materials. This method exhibits high synthetic efficiency, high stereoselectivity, and high variability of substituent.