%0 Journal Article
%A Hu, Tuoping
%A Bi, Wenhua
%A Hu, Xiaoqin
%A Zhao, Xiaoliang
%A Sun, Daofeng
%D 2010
%T Construction of Metal−Organic Frameworks with Novel {Zn8O13} SBU or Chiral Channels through in Situ Ligand Reaction
%U https://acs.figshare.com/articles/journal_contribution/Construction_of_Metal_Organic_Frameworks_with_Novel_Zn_sub_8_sub_O_sub_13_sub_SBU_or_Chiral_Channels_through_i_in_Situ_i_Ligand_Reaction/2746168
%R 10.1021/cg100725j.s004
%2 https://ndownloader.figshare.com/files/4425292
%K H 3DTIM ligands
%K H 3IMDC
%K Complex
%K acid
%K Situ Ligand ReactionBy control
%K di
%K complex
%K Framework
%K Construction
%K topology
%K Chiral
%K Zn 8O SBU
%K framework
%K MOF
%K hydrothermally
%K precursor
%K homochiral
%X By control of in situ ligand reaction, two zinc metal−organic frameworks (1, 2) have been isolated hydrothermally. Both complexes are 3D open frameworks. Complex 1, which is based on an unprecedented {Zn8O13} SBU constructed of 2H-imidazole-4,5-dicarboxylic acid (H3IMDC), has the same topology as that of MOF-5. Complex 2 contains large homochiral channels based on the in situ generated 4,5-di(1H-tetrazol-5-yl)-2H-imidazole (H3DTIM). Both H3IMDC and H3DTIM ligands are in situ generated from the same precursor, 2H-imidazole-4,5-dicarbonitrile.
%I ACS Publications