TY - DATA T1 - Highly Efficient and Expedient Synthesis of 5-Hydroxy-1H-pyrrol-2-(5H)-ones from FeCl3-Catalyzed Tandem Intramolecular Enaminic Addition of Tertiary Enamides to Ketones and 1,3-Hydroxy Rearrangement PY - 2010/09/03 AU - Luo Yang AU - Chuan-Hu Lei AU - De-Xian Wang AU - Zhi-Tang Huang AU - Mei-Xiang Wang UR - https://acs.figshare.com/articles/dataset/Highly_Efficient_and_Expedient_Synthesis_of_5_Hydroxy_1_i_H_i_pyrrol_2_5_i_H_i_ones_from_FeCl_sub_3_sub_Catalyzed_Tandem_Intramolecular_Enaminic_Addition_of_Tertiary_Enamides_to_Ketones_and_1_3_Hydroxy_Rearrangement/2735926 DO - 10.1021/ol101607z.s002 L4 - https://ndownloader.figshare.com/files/4412665 KW - Efficient KW - enamide KW - Expedient Synthesis KW - Tandem KW - ketonic carbonyls KW - intramolecular enaminic addition reaction KW - Ketone KW - Rearrangement KW - FeCl 3 KW - Catalyzed KW - Hydroxy KW - Enaminic KW - yield KW - Tertiary Enamides KW - Intramolecular KW - rearrangement KW - hydroxy N2 - Catalyzed by FeCl3 under very mild conditions, tertiary enamides underwent a highly efficient intramolecular enaminic addition reaction to the ketonic carbonyls followed by 1,3-hydroxy rearrangement to produce 5-hydroxy-1H-pyrrol-2(5H)-ones in excellent yields. ER -