%0 Generic %A Yang, Luo %A Lei, Chuan-Hu %A Wang, De-Xian %A Huang, Zhi-Tang %A Wang, Mei-Xiang %D 2010 %T Highly Efficient and Expedient Synthesis of 5-Hydroxy-1H-pyrrol-2-(5H)-ones from FeCl3-Catalyzed Tandem Intramolecular Enaminic Addition of Tertiary Enamides to Ketones and 1,3-Hydroxy Rearrangement %U https://acs.figshare.com/articles/dataset/Highly_Efficient_and_Expedient_Synthesis_of_5_Hydroxy_1_i_H_i_pyrrol_2_5_i_H_i_ones_from_FeCl_sub_3_sub_Catalyzed_Tandem_Intramolecular_Enaminic_Addition_of_Tertiary_Enamides_to_Ketones_and_1_3_Hydroxy_Rearrangement/2735926 %R 10.1021/ol101607z.s002 %2 https://ndownloader.figshare.com/files/4412665 %K Efficient %K enamide %K Expedient Synthesis %K Tandem %K ketonic carbonyls %K intramolecular enaminic addition reaction %K Ketone %K Rearrangement %K FeCl 3 %K Catalyzed %K Hydroxy %K Enaminic %K yield %K Tertiary Enamides %K Intramolecular %K rearrangement %K hydroxy %X Catalyzed by FeCl3 under very mild conditions, tertiary enamides underwent a highly efficient intramolecular enaminic addition reaction to the ketonic carbonyls followed by 1,3-hydroxy rearrangement to produce 5-hydroxy-1H-pyrrol-2(5H)-ones in excellent yields. %I ACS Publications