10.1021/ol101611v.s003 Peizhong Xie Peizhong Xie You Huang You Huang Ruyu Chen Ruyu Chen Phosphine-Catalyzed Domino Reaction: Highly Stereoselective Synthesis of <i>trans</i>-2,3-Dihydrobenzofurans from Salicyl <i>N</i>-Thiophosphinyl Imines and Allylic Carbonates American Chemical Society 2010 skeleton domino Imine Stereoselective Synthesis Allylic Carbonates Salicyl imine diastereoselectivity approach dipolar salicyl method synthon allylic carbonates kind Domino tran allylic carbonate construction 2010-09-03 00:00:00 Dataset https://acs.figshare.com/articles/dataset/Phosphine_Catalyzed_Domino_Reaction_Highly_Stereoselective_Synthesis_of_i_trans_i_2_3_Dihydrobenzofurans_from_Salicyl_i_N_i_Thiophosphinyl_Imines_and_Allylic_Carbonates/2735920 A novel phosphine-catalyzed domino reaction of salicyl <i>N</i>-thiophosphinyl imines and allylic carbonates was developed. The allylic carbonate, in this reaction, serves as a new kind of 1,1-dipolar synthon. This method offered a powerful approach to the construction of a highly substituted <i>trans</i>-2,3-dihydrobenzofuran skeleton with high diastereoselectivity.