TY - DATA T1 - Practical Approach to Structurally Diverse Monoimine Salts and Nonsymmetrical Metallosalphen Complexes PY - 2010/10/15 AU - Eduardo C. Escudero-Adán AU - Marta Martínez Belmonte AU - Jordi Benet-Buchholz AU - Arjan W. Kleij UR - https://acs.figshare.com/articles/journal_contribution/Practical_Approach_to_Structurally_Diverse_Monoimine_Salts_and_Nonsymmetrical_Metallosalphen_Complexes/2721799 DO - 10.1021/ol101898y.s004 L4 - https://ndownloader.figshare.com/files/4397758 KW - nucleophilic addition KW - complex KW - hydrolysis KW - monoimine NBu 4 salts KW - Practical Approach KW - Nonsymmetrical Metallosalphen Complexes KW - imine bond KW - approach KW - method KW - synthesis KW - Zn KW - hydroxide anion KW - chiral KW - reagent KW - Structurally Diverse Monoimine Salts KW - metallosalen N2 - A practical approach toward the synthesis of monoimine NBu4 salts derived from Zn(salphen) complexes is described. The method involves nucleophilic addition of the hydroxide anion to the imine bond followed by hydrolysis. These monoimines provide accessible and useful reagents for the synthesis of (chiral) metallosalens with fine-tunable properties. ER -