Practical Approach to Structurally Diverse Monoimine Salts and Nonsymmetrical Metallosalphen Complexes
Eduardo C. Escudero-Adán
Marta Martínez Belmonte
Jordi Benet-Buchholz
Arjan W. Kleij
10.1021/ol101898y.s004
https://acs.figshare.com/articles/journal_contribution/Practical_Approach_to_Structurally_Diverse_Monoimine_Salts_and_Nonsymmetrical_Metallosalphen_Complexes/2721799
A practical approach toward the synthesis of monoimine NBu<sub>4</sub> salts derived from Zn(salphen) complexes is described. The method involves nucleophilic addition of the hydroxide anion to the imine bond followed by hydrolysis. These monoimines provide accessible and useful reagents for the synthesis of (chiral) metallosalens with fine-tunable properties.
2010-10-15 00:00:00
nucleophilic addition
complex
hydrolysis
monoimine NBu 4 salts
Practical Approach
Nonsymmetrical Metallosalphen Complexes
imine bond
approach
method
synthesis
Zn
hydroxide anion
chiral
reagent
Structurally Diverse Monoimine Salts
metallosalen