Synthesis and RCM Reactions Using a Recyclable Grubbs−Hoveyda Metathesis Catalyst Activated by a Light Fluorous Tag
Masato Matsugi
Yuki Kobayashi
Naoki Suzumura
Yuki Tsuchiya
Takayuki Shioiri
10.1021/jo101140w.s001
https://acs.figshare.com/articles/journal_contribution/Synthesis_and_RCM_Reactions_Using_a_Recyclable_Grubbs_Hoveyda_Metathesis_Catalyst_Activated_by_a_Light_Fluorous_Tag/2711206
A recyclable Grubbs−Hoveyda second-generation catalyst activated by a light fluorous tag was prepared. The modified light fluorous catalyst exhibited higher catalytic activity than the parent or the previously reported light fluorous variant for RCM reactions and could be routinely recovered. The light fluorous tag incorporated in the catalyst served as both an activator as well as a handle for separation and recovery with fluorous solid-phase extraction.
2010-11-19 00:00:00
Light Fluorous TagA
Grubb
RCM Reactions
RCM reactions
light fluorous tag
light fluorous variant
light fluorous catalyst