TY - DATA T1 - Dienyl Homoallyl Alcohols via Palladium Catalyzed Ene-Type Reaction of Aldehydes with 1,3-Dienes PY - 2010/11/24 AU - Masahiro Fukushima AU - Daiki Takushima AU - Masanari Kimura UR - https://acs.figshare.com/articles/journal_contribution/Dienyl_Homoallyl_Alcohols_via_Palladium_Catalyzed_Ene_Type_Reaction_of_Aldehydes_with_1_3_Dienes/2710249 DO - 10.1021/ja1072417.s001 L4 - https://ndownloader.figshare.com/files/4386196 KW - presence KW - allylation KW - Xantphos ligand KW - diene KW - Aldehyde KW - Dienyl Homoallyl Alcohols KW - electron density KW - Et 3B KW - aldehyde KW - Palladium KW - dienyl homoallyl alcohols KW - combination KW - Pd catalyst KW - Catalyzed KW - DienesThe KW - yield KW - bond N2 - The combination of Pd catalyst and Xantphos ligand in the presence of Et3B nicely promotes the allylation of aldehydes with conjugated dienes to provide dienyl homoallyl alcohols in excellent yields. The reaction occurs selectively at the C−C double bond bearing higher electron density. ER -