Chiral Diene as the Ligand for the Synthesis of Axially Chiral Compounds via Palladium-Catalyzed Suzuki−Miyaura Coupling Reaction Shu-Sheng Zhang Zhi-Qian Wang Ming-Hua Xu Guo-Qiang Lin 10.1021/ol102521q.s001 https://acs.figshare.com/articles/journal_contribution/Chiral_Diene_as_the_Ligand_for_the_Synthesis_of_Axially_Chiral_Compounds_via_Palladium_Catalyzed_Suzuki_Miyaura_Coupling_Reaction/2707972 The first palladium−diene-catalyzed asymmetric Suzuki−Miyaura coupling reaction has been achieved. A number of functionalized biaryls were obtained in high yields and in moderate to high enantioselectivities. The existence of an <i>ortho</i>-formyl group greatly improves the catalyst efficiency and permits further synthetic elaborations. 2010-12-03 00:00:00 Chiral Diene Axially Chiral Compounds Suzuki Ligand functionalized biaryls catalyst efficiency Synthesi elaboration palladium yield enantioselectivitie