Gao, Ruili Yi, Chae S. Catalytic Formation of Silyl Enol Ethers and Its Applications for Aldol-Type Condensation and Aminomethylation Reactions A new catalytic method for the synthesis of silyl enol ethers has been developed from the coupling reaction of ketones with CH<sub>2</sub>CHSiMe<sub>3</sub> by using a ruthenium hydride catalyst (PCy<sub>3</sub>)<sub>2</sub>(CO)RuHCl. The synthetic utility of silyl enol ethers was demonstrated for both Mukaiyama aldol condensation and aminomethylation reactions in forming β-hydroxyketones and β-aminoketones, respectively. aminomethylation reactions;Application;CH;utility;PCy;silyl enol ethers;Catalytic Formation;method;Mukaiyama aldol condensation;synthesis;Condensation;Silyl Enol Ethers;hydroxyketone;ruthenium hydride catalyst;Aminomethylation ReactionsA;ketone;aminoketone 2011-05-06
    https://acs.figshare.com/articles/journal_contribution/Catalytic_Formation_of_Silyl_Enol_Ethers_and_Its_Applications_for_Aldol_Type_Condensation_and_Aminomethylation_Reactions/2655295
10.1021/cs200087c.s001