Rohr, Ahleah D. M. Banaszak Holl, Mark Kampf, Jeff W. Ashe, Arthur J. 2<i>H</i>-1,2-Thiaborin: A New Boron–Sulfur Heterocycle The reaction of 2,5-dihydro-2-diisopropylamino-1,2-thiaborole (<b>5</b>) with 2 equiv of LDA followed by CH<sub>2</sub>Cl<sub>2</sub> gives 2-(diisopropylamino)-2<i>H</i>-1,2-thiaborin (<b>2c</b>), which has been spectroscopically and structurally characterized. DFT calculations indicate that formally aromatic <b>2c</b> has a limited π-delocalized bonding in its heterocyclic ring. diisopropylamino;heterocyclic ring;2 equiv;HeterocycleThe;New;CH 2Cl;LDA;Boron;delocalized;2 c;DFT calculations;spectroscopically;dihydro 2011-07-25
    https://acs.figshare.com/articles/dataset/2_i_H_i_1_2_Thiaborin_A_New_Boron_Sulfur_Heterocycle/2629064
10.1021/om200400j.s002