Arroyo, Yolanda Sanz-Tejedor, M. Ascensión Alonso, Inés García-Ruano, José L. Synthesis of Optically Pure <i>vic</i>-Sulfanyl Amines Mediated by a Remote Sulfinyl Group Enantiomerically pure <i>syn</i>-1,2-diaryl-1,2-sulfanylamine derivatives can be obtained in a completely stereoselective manner by reaction of the benzylcarbanion Li-(<i>S</i>)-<b>1</b> with <i>N</i>-phenyl (or PMP)-arylidene aldimines and further desulfinylation with <i>t</i>-BuLi. Theoretical studies at the DFT (mPW1PW91) level with the CPCM model, by using the Gaussian09 program, provide a good explanation for the stereochemical results. Li;Mediated;Pure;stereochemical results;Optically;PMP;CPCM model;desulfinylation;benzylcarbanion;derivative;Gaussian 09 program;Synthesi;Remote Sulfinyl GroupEnantiomerically;DFT;mPW 1PW level;syn;stereoselective manner;Theoretical studies;aldimine;Amine 2011-09-02
    https://acs.figshare.com/articles/dataset/Synthesis_of_Optically_Pure_i_vic_i_Sulfanyl_Amines_Mediated_by_a_Remote_Sulfinyl_Group/2618269
10.1021/ol201696y.s001