Structural Revision and Total Synthesis of Caraphenol B and C
Scott A. Snyder
Zachary G. Brill
10.1021/ol2022406.s002
https://acs.figshare.com/articles/dataset/Structural_Revision_and_Total_Synthesis_of_Caraphenol_B_and_C/2597743
Chemical syntheses of two stereochemically unique resveratrol dimers, caraphenols B and C, have shown that their structures are misassigned. Thoughts on their potential chemical etiology led to an alternate structural proposal that has been confirmed through synthesis, one indicating that the substituents on their respective indane systems exist in a relative <i>trans,trans</i> orientation rather than the originally postulated all-<i>cis</i> arrangement.
2011-10-21 00:00:00
indane systems
orientation
misassigned
Structural Revision
arrangement
proposal
chemical etiology
Caraphenol B
CChemical syntheses
substituent
stereochemically
Total Synthesis
caraphenols B
tran
synthesis
resveratrol dimers