%0 Generic %A Smeekens, Sylvia %A Heylen, Steven %A Janssens, Nikki, %A Houthoofd, Kristof %A Martens, Johan A. %A E. A. Kirschhock, Christine %D 2016 %T NOx Adsorption Site Engineering in Ru/Ba,Na–Y Zeolite %U https://acs.figshare.com/articles/dataset/NO_sub_i_x_i_sub_Adsorption_Site_Engineering_in_Ru_Ba_Na_Y_Zeolite/2594533 %R 10.1021/cm202230r.s007 %2 https://ndownloader.figshare.com/files/4241989 %K Ru %K zeolite frameworks %K adsorption studies %K adsorption strength %K zeolite Y %K zeolite properties %K performant NOx adsorbent %K gas molecules %K NMR %K NOx Adsorption Site Engineering %K cation distribution %X Adsorption of gas molecules is a typical application for zeolites. Interaction of adsorbed molecules with cations in zeolite frameworks is responsible for selectivity and adsorption strength. Through detailed analysis of the cation distribution in zeolite Y containing Na+, Ba2+, and Ru3+ cations by NMR and X-ray diffraction combined with adsorption studies it was possible to develop a reversible, highly performant NOx adsorbent. The results demonstrate intimate understanding of guest–host interactions can lead to rational tailoring of zeolite properties. %I ACS Publications