%0 Generic
%A Smeekens, Sylvia
%A Heylen, Steven
%A Janssens, Nikki,
%A Houthoofd, Kristof
%A Martens, Johan A.
%A E. A. Kirschhock, Christine
%D 2016
%T NOx Adsorption Site Engineering in Ru/Ba,Na–Y Zeolite
%U https://acs.figshare.com/articles/dataset/NO_sub_i_x_i_sub_Adsorption_Site_Engineering_in_Ru_Ba_Na_Y_Zeolite/2594533
%R 10.1021/cm202230r.s007
%2 https://ndownloader.figshare.com/files/4241989
%K Ru
%K zeolite frameworks
%K adsorption studies
%K adsorption strength
%K zeolite Y
%K zeolite properties
%K performant NOx adsorbent
%K gas molecules
%K NMR
%K NOx Adsorption Site Engineering
%K cation distribution
%X Adsorption of gas molecules is a typical application for zeolites. Interaction of adsorbed molecules with cations in zeolite frameworks is responsible for selectivity and adsorption strength. Through detailed analysis of the cation distribution in zeolite Y containing Na+, Ba2+, and Ru3+ cations by NMR and X-ray diffraction combined with adsorption studies it was possible to develop a reversible, highly performant NOx adsorbent. The results demonstrate intimate understanding of guest–host interactions can lead to rational tailoring of zeolite properties.
%I ACS Publications