%0 Journal Article
%A Doud, Michael
D.
%A Grice, Kyle A.
%A Lilio, Alyssia M.
%A Seu, Candace S.
%A Kubiak, Clifford P.
%D 2012
%T Versatile Synthesis of
PR2NR′2 Ligands
for Molecular Electrocatalysts
with Pendant Bases in the Second Coordination Sphere
%U https://acs.figshare.com/articles/journal_contribution/Versatile_Synthesis_of_P_sup_R_sup_sub_2_sub_N_sup_R_sup_sub_2_sub_Ligands_for_Molecular_Electrocatalysts_with_Pendant_Bases_in_the_Second_Coordination_Sphere/2551135
%R 10.1021/om201168h.s001
%2 https://ndownloader.figshare.com/files/4194193
%K Ni
%K 1 H NMR
%K Pendant Bases
%K Molecular Electrocatalysts
%K Versatile Synthesis
%K PR 2NR Ligands
%K PBn 2NPh
%K phosphine substituent
%K P 2N ligands
%K PMe 2NPh
%X Two 1,5-diaza-3,7-diphosphacyclooctane (P2N2) ligands with alkyl-substituted phosphines have been
synthesized
via a versatile method that allows for improved control of the phosphine
substituent. The methyl- and benzyl-substituted phosphine P2N2 ligands (PMe2NPh2 and PBn2NPh2)
were synthesized and characterized by 31P{1H}
NMR, 1H NMR, and elemental analysis, and their corresponding
[Ni(PR2NPh2)2](BF4)2 complexes were synthesized and characterized
by 31P{1H} NMR, 1H NMR, and electrochemistry.
The structure of the complex [Ni(PMe2NPh2)2](CF3SO3)2 was characterized by X-ray crystallography.
%I ACS Publications