Orellana, Arturo Pandey, Sushil K. Carret, Sébastien Greene, Andrew E. Poisson, Jean-François A Diels–Alder-Based Total Synthesis of (−)-Kainic Acid An efficient synthesis of (−)-kainic acid, through a high-pressure-promoted Diels–Alder cycloaddition of a vinylogous malonate derived from 4-hydroxyproline, is described. The bicyclic adduct could be converted into the natural product with complete stereocontrol. kainic;acid;AcidAn;cycloaddition;Diel;synthesis;hydroxyproline;bicyclic adduct;stereocontrol;Kainic;Synthesi;vinylogous malonate 2012-06-15
    https://acs.figshare.com/articles/journal_contribution/A_Diels_Alder_Based_Total_Synthesis_of_Kainic_Acid/2513251
10.1021/jo300608g.s001