TY - DATA T1 - NCN Pincer–Pt Complexes Coordinated by (Nitronyl Nitroxide)-2-ide Radical Anion PY - 2012/10/31 AU - Xun Zhang AU - Shuichi Suzuki AU - Masatoshi Kozaki AU - Keiji Okada UR - https://acs.figshare.com/articles/dataset/NCN_Pincer_Pt_Complexes_Coordinated_by_Nitronyl_Nitroxide_2_ide_Radical_Anion/2474158 DO - 10.1021/ja308103g.s004 L4 - https://ndownloader.figshare.com/files/4116859 KW - nitronyl nitroxide moiety KW - Pt complexes KW - crystal structure analyses KW - NCN N2 - New pincer–Pt complexes coordinated by (nitronyl nitroxide)-2-ide radical anion were prepared as stable compounds in high yields. The structures of these Pt complexes and the oxidized complexes were unequivocally determined by spectral and crystal structure analyses. The oxidation potential of the nitronyl nitroxide moiety in these complexes was shifted in the negative direction by ∼0.6 V as a result of coordination to the Pt­(II) atom. ER -