10.1021/ja308103g.s006
Xun Zhang
Xun
Zhang
Shuichi Suzuki
Shuichi
Suzuki
Masatoshi Kozaki
Masatoshi
Kozaki
Keiji Okada
Keiji
Okada
NCN Pincer–Pt Complexes
Coordinated by (Nitronyl
Nitroxide)-2-ide Radical Anion
American Chemical Society
2012
nitronyl nitroxide moiety
Pt complexes
crystal structure analyses
NCN
2012-10-31 00:00:00
Journal contribution
https://acs.figshare.com/articles/journal_contribution/NCN_Pincer_Pt_Complexes_Coordinated_by_Nitronyl_Nitroxide_2_ide_Radical_Anion/2474152
New pincer–Pt complexes coordinated by (nitronyl
nitroxide)-2-ide
radical anion were prepared as stable compounds in high yields. The
structures of these Pt complexes and the oxidized complexes were unequivocally
determined by spectral and crystal structure analyses. The oxidation
potential of the nitronyl nitroxide moiety in these complexes was
shifted in the negative direction by ∼0.6 V as a result of
coordination to the Pt(II) atom.