%0 Journal Article %A Hernández-Gil, J. %A Ovèjak, N. %A Ferrer, S. %A Lloret, F. %A Castiñeiras, A. %D 2016 %T Novel Hexanuclear Copper(II) Complex Built from a Simple Tetrachelating Triazole Ligand: Synthesis, Structure, and Magnetism %U https://acs.figshare.com/articles/journal_contribution/Novel_Hexanuclear_Copper_II_Complex_Built_from_a_Simple_Tetrachelating_Triazole_Ligand_Synthesis_Structure_and_Magnetism/2438059 %R 10.1021/ic3027946.s001 %2 https://ndownloader.figshare.com/files/4080715 %K constant %K cm %K Hexanuclear %K binding %K mode %K Complex %K ratio %K ligand %K Simple Tetrachelating Triazole Ligand %K MagnetismA %K type %K Synthesi %K triazole %K CuII centers %K bi %K novel hexanuclear compound %K antiferromagnetic %K disubstituted %K H 3diV %X A new easy symmetric 3,5-disubstituted 1,2,4-triazole ligand (H3diV) by reaction with an excess of copper­(II) salt has afforded a novel hexanuclear compound (Cu/HdiV ratio of 6:2) through a bis­(trans–cis–cis–trans) binding mode, exhibiting two types of CuII centers and two clearly distinguishable antiferromagnetic J1 (−234 cm–1) and J2 (−35 cm–1) coupling constants. %I ACS Publications