%0 Journal Article
%A Hernández-Gil, J.
%A Ovèjak, N.
%A Ferrer, S.
%A Lloret, F.
%A Castiñeiras, A.
%D 2016
%T Novel Hexanuclear
Copper(II) Complex Built from a Simple Tetrachelating Triazole Ligand:
Synthesis, Structure, and Magnetism
%U https://acs.figshare.com/articles/journal_contribution/Novel_Hexanuclear_Copper_II_Complex_Built_from_a_Simple_Tetrachelating_Triazole_Ligand_Synthesis_Structure_and_Magnetism/2438059
%R 10.1021/ic3027946.s001
%2 https://ndownloader.figshare.com/files/4080715
%K constant
%K cm
%K Hexanuclear
%K binding
%K mode
%K Complex
%K ratio
%K ligand
%K Simple Tetrachelating Triazole Ligand
%K MagnetismA
%K type
%K Synthesi
%K triazole
%K CuII centers
%K bi
%K novel hexanuclear compound
%K antiferromagnetic
%K disubstituted
%K H 3diV
%X A new easy symmetric 3,5-disubstituted
1,2,4-triazole ligand (H3diV) by reaction with an excess
of copper(II) salt has afforded a novel hexanuclear compound (Cu/HdiV
ratio of 6:2) through a bis(trans–cis–cis–trans)
binding mode, exhibiting two types of CuII centers and
two clearly distinguishable antiferromagnetic J1 (−234 cm–1) and J2 (−35 cm–1) coupling constants.
%I ACS Publications