TY - DATA T1 - Structural Diversities and Fluorescent and Photocatalytic Properties of a Series of CuII Coordination Polymers Constructed from Flexible Bis-pyridyl-bis-amide Ligands with Different Spacer Lengths and Different Aromatic Carboxylates PY - 2013/08/07 AU - Xiu-Li Wang AU - Jian Luan AU - Fang-Fang Sui AU - Hong-Yan Lin AU - Guo-Cheng Liu AU - Chuang Xu UR - https://acs.figshare.com/articles/dataset/Structural_Diversities_and_Fluorescent_and_Photocatalytic_Properties_of_a_Series_of_Cu_sup_II_sup_Coordination_Polymers_Constructed_from_Flexible_Bis_pyridyl_bis_amide_Ligands_with_Different_Spacer_Lengths_and_Different_Aromatic_Carboxylates/2389414 DO - 10.1021/cg400538c.s002 L4 - https://ndownloader.figshare.com/files/4029103 KW - 13 exhibits KW - Complex 4 exhibits KW - Complexes 5 KW - Complex 1 features KW - Different Spacer Lengths KW - CuII Coordination Polymers Constructed KW - show 2 D networks KW - 2 D KW - 1 D zigzag chain KW - Photocatalytic Properties KW - sql topology KW - 2BDC KW - layer structures KW - 3BTC KW - BDC KW - Complex 3 KW - Different Aromatic CarboxylatesThirteen KW - point symbol KW - NDC KW - ligand exhibit KW - CuII coordination polymers KW - Structural Diversities KW - photocatalytic properties KW - Complex 2 KW - ligand show KW - 2NDC KW - title complexes N2 - Thirteen new CuII coordination polymers, namely, [Cu­(3-dppa)­(1,3,5-HBTC)] (1), [Cu­(3-dpha)­(1,3,5-HBTC)­(H2O)]­·H2O (2), [Cu3(3-dpsea)­(1,3,5-BTC)2­(H2O)5]·4H2O (3), [Cu­(3-dpba)­(1,2-BDC)]­·H2O (4), [Cu­(3-dpha)­(1,2-BDC)] (5), [Cu­(3-dpsea)­(1,2-BDC)]­·H2O (6), [Cu2(3-dpyp)­(1,3-BDC)2­(H2O)4]­·3H2O (7), [Cu­(3-dppa)­(1,3-BDC)­(H2O)]­·2H2O (8), [Cu­(3-dppia)­(1,3-BDC)­(H2O)2]­·2H2O (9), [Cu2(3-dpsea)2­(1,3-BDC)2­(H2O)2]­·7H2O (10), [Cu­(3-dpba)­(1,4-NDC)]­·3H2O (11), [Cu­(3-dpyh)­(1,4-NDC)­(H2O)]­·3H2O (12), [Cu­(3-dpyh)0.5­(1,4-NDC)]­·H2O (13), have been purposefully synthesized under hydrothermal conditions [3-dppa = N,N′-di­(3-pyridyl)­propanediamide, 3-dpba = N,N′-di­(3-pyridyl)­butanediamide, 3-dpha = N,N′-di­(3-pyridyl)­hexanedioicdiamide, 3-dppia = N,N′-di­(3-pyridyl)­pimelicdiamide, 3-dpsea = N,N′-di­(3-pyridyl)­sebacicdiamide, 3-dpyp = N,N′-di­(3-pyridine­carboxamide)-1,3-propane, 3-dpyh = N,N′-di­(3-pyridine­carboxamide)-1,6-hexane, 1,3,5-H3BTC = 1,3,5-benzenetricarboxylic acid, 1,2-H2BDC = 1,2-benzenedicarboxylic acid, 1,3-H2BDC = 1,3-benzenedicarboxylic acid and 1,4-H2NDC = 1,4-naphthalenedicarboxylic acid]. Complexes 1–3 based on the same auxiliary ligand show various structures. Complex 1 features a one-dimensional (1D) ∞-like double-chain structure, which consists of a [Cu-1,3,5-HBTC]n chain and [Cu-3-dppa]n meso-helical chain. Complex 2 possesses a (2,4) undulated honeycomb (hcb) net. Complex 3 is a 3-fold interpenetrating three-dimensional (3D) framework, which shows trinodal (2,3,3)-connected topology with the Schläfli symbol of (10·122)2(103)2(12). Complexes 4–6 with 1,2-BDC as secondary ligand exhibit different two-dimensional (2D) layer structures. Complex 4 exhibits a 2D (2,4)-connected (4·124·14)­(4) net. Complexes 5 and 6 have similar structures and show 2D networks with undulated sql topology. For complexes 7–10 based on 1,3-BDC secondary ligand, complex 7 shows a 1D zigzag chain, while complexes 8–10 have similar wave-like 2D structures. When 1,4-NDC was used as the auxiliary ligand, complex 11 is a 2D puckered (4,4) network, complex 12 reveals a 4-connected topology with the point symbol of (44·62), while complex 13 exhibits a 3-fold interpenetrating 3D α-Po framework. The structural diversity indicates that the bis-pyridyl-bis-amide ligands with different spacers and the aromatic polycarboxylates play important roles in tuning the dimensionalities and structures of the title complexes. The fluorescent and photocatalytic properties for 1–13 have also been investigated in detail. ER -