10.1021/cg400500t.s001 Huong Giang T. Nguyen Huong Giang T. Nguyen Mitchell H. Weston Mitchell H. Weston Amy A. Sarjeant Amy A. Sarjeant Daniel M. Gardner Daniel M. Gardner Zhi An Zhi An Raanan Carmieli Raanan Carmieli Michael R. Wasielewski Michael R. Wasielewski Omar K. Farha Omar K. Farha Joseph T. Hupp Joseph T. Hupp SonBinh T. Nguyen SonBinh T. Nguyen Design, Synthesis, Characterization, and Catalytic Properties of a Large-Pore Metal-Organic Framework Possessing Single-Site Vanadyl(monocatecholate) Moieties American Chemical Society 2016 exhibit presence pore tetralin Vanadyl moiety Catalytic Properties Framework vanadyl Synthesi combination paddlewheel MOF postsynthesis deprotection dipyridyl struts Characterization MoietiesThrough Possessing benzylic oxidation postsynthesis metallation 2016-02-19 01:45:14 Journal contribution https://acs.figshare.com/articles/journal_contribution/Design_Synthesis_Characterization_and_Catalytic_Properties_of_a_Large_Pore_Metal_Organic_Framework_Possessing_Single_Site_Vanadyl_monocatecholate_Moieties/2389411 Through a combination of protecting groups, postsynthesis deprotection, and postsynthesis metallation, a homogeneously inaccessible, single-site vanadyl­(monocatecholate) moiety can be incorporated into the dipyridyl struts of a Zn-based, pillared paddlewheel MOF. The resulting MOF, which has large pores, exhibits catalytic activity in the benzylic oxidation of tetralin in the presence of <i>tert</i>-butylhydroperoxide.