10.1021/cg400500t.s001
Huong
Giang T. Nguyen
Huong
Giang T.
Nguyen
Mitchell
H. Weston
Mitchell
H.
Weston
Amy A. Sarjeant
Amy A.
Sarjeant
Daniel M. Gardner
Daniel M.
Gardner
Zhi An
Zhi
An
Raanan Carmieli
Raanan
Carmieli
Michael R. Wasielewski
Michael R.
Wasielewski
Omar K. Farha
Omar K.
Farha
Joseph T. Hupp
Joseph T.
Hupp
SonBinh T. Nguyen
SonBinh T.
Nguyen
Design, Synthesis, Characterization, and Catalytic
Properties of a Large-Pore Metal-Organic Framework Possessing Single-Site
Vanadyl(monocatecholate) Moieties
American Chemical Society
2016
exhibit
presence
pore
tetralin
Vanadyl
moiety
Catalytic Properties
Framework
vanadyl
Synthesi
combination
paddlewheel MOF
postsynthesis deprotection
dipyridyl struts
Characterization
MoietiesThrough
Possessing
benzylic oxidation
postsynthesis metallation
2016-02-19 01:45:14
Journal contribution
https://acs.figshare.com/articles/journal_contribution/Design_Synthesis_Characterization_and_Catalytic_Properties_of_a_Large_Pore_Metal_Organic_Framework_Possessing_Single_Site_Vanadyl_monocatecholate_Moieties/2389411
Through a combination of protecting
groups, postsynthesis deprotection,
and postsynthesis metallation, a homogeneously inaccessible, single-site
vanadyl(monocatecholate) moiety can be incorporated into the dipyridyl
struts of a Zn-based, pillared paddlewheel MOF. The resulting MOF,
which has large pores, exhibits catalytic activity in the benzylic
oxidation of tetralin in the presence of <i>tert</i>-butylhydroperoxide.