%0 Journal Article
%A Ma, Huiqing
%A Sun, Di
%A Zhang, Liangliang
%A Wang, Rongming
%A Blatov, Vladislav A.
%A Guo, Jie
%A Sun, Daofeng
%D 2013
%T A “Strongly”
Self-Catenated Metal–Organic Framework with the Highest Topological
Density among 3,4-Coordinated Nets
%U https://acs.figshare.com/articles/journal_contribution/A_Strongly_Self_Catenated_Metal_Organic_Framework_with_the_Highest_Topological_Density_among_3_4_Coordinated_Nets/2369698
%R 10.1021/ic4018757.s002
%2 https://ndownloader.figshare.com/files/4009189
%K topological density
%K building units
%K H 3L
%K coordination network
%K Topological Density
%K tripodal carboxylate linker
%K SDU
%K Cu
%X A new
type of 3D “strongly” self-catenated metal–organic
framework (SDU-9) has been constructed from [Cu2(COO)4] paddlewheel secondary building units and a tripodal
carboxylate linker. SDU-9 ([Cu6(H2O)6L4]·24H2O,
where [H3L = 4,4′,4″-(hydroxysilanetriyl)tris(triphenyl-4-carboxylic
acid), represents a rare example of a highly symmetrical coordination
network and extremely tight self-catenation. To the best of our knowledge, SDU-9 has the highest topological density among all known
3,4-coordinated nets.
%I ACS Publications