10.1021/om400651p.s002
Aleksandrs Prokofjevs
Aleksandrs
Prokofjevs
Janis Jermaks
Janis
Jermaks
Alina Borovika
Alina
Borovika
Jeff W. Kampf
Jeff W.
Kampf
Edwin Vedejs
Edwin
Vedejs
Electrophilic C–H Borylation and Related Reactions
of B–H Boron Cations
American Chemical Society
2013
Related Reactions
center
borylation
2013-11-25 00:00:00
Journal contribution
https://acs.figshare.com/articles/journal_contribution/Electrophilic_C_H_Borylation_and_Related_Reactions_of_B_H_Boron_Cations/2350675
Catalytic
procedures are described for the amine-directed borylation
of aliphatic and aromatic tertiary amine–boranes. Sequential
double borylation is observed in cases where two or more C–H
bonds are available that allow 5-center or 6-center intramolecular
borylation. The HNTf<sub>2</sub>-catalyzed borylation of benzylamine–boranes
provides a practical means for the synthesis of ortho-substituted
arylboronic acid derivatives, suitable for Suzuki–Miyaura cross-coupling
applications.