Qian, Jieshu Li, Xiaoyu Lunn, David J. Gwyther, Jessica Hudson, Zachary M. Kynaston, Emily Rupar, Paul A. Winnik, Mitchell A. Manners, Ian Uniform, High Aspect Ratio Fiber-like Micelles and Block Co-micelles with a Crystalline π‑Conjugated Polythiophene Core by Self-Seeding Monodisperse fiber-like micelles with a crystalline π-conjugated poly­thiophene core with lengths up to ca. 700 nm were successfully prepared from the diblock co­polymer poly­(3-hexyl­thiophene)-<i>block</i>-poly­styrene using a one-dimensional self-seeding technique. Addition of a poly­thiophene block co­polymer with a different corona-forming block to the resulting nanofibers led to the formation of segmented B-A-B triblock co-micelles by crystallization-driven seeded growth. The key to these advances appears to be the formation of a relatively defect-free crystalline micelle core under the self-seeding conditions. micelle core;poly;formation;700 nm 2014-03-19
    https://acs.figshare.com/articles/journal_contribution/Uniform_High_Aspect_Ratio_Fiber_like_Micelles_and_Block_Co_micelles_with_a_Crystalline_Conjugated_Polythiophene_Core_by_Self_Seeding/2313682
10.1021/ja500661k.s001