Pepper, Henry P. Tulip, Stephen J. Nakano, Yuji George, Jonathan H. Biomimetic Total Synthesis of (±)-Doitunggarcinone A and (+)-Garcibracteatone A full account of our oxidative radical cyclization approach to the synthesis of garcibracteatone and doitunggarcinone A is presented. This includes the first enantioselective synthesis of garcibracteatone, which allowed the absolute configuration of the natural compound to be determined. The first synthesis of doitunggarcinone A is also described, which confirms our reassignment of the relative configuration of this molecule. Novel syntheses of monoterpene fragments used to construct the target molecules are also reported. garcibracteatone;monoterpene fragments;target molecules;cyclization approach;Novel syntheses;enantioselective synthesis;doitunggarcinone;configuration 2014-03-21
    https://acs.figshare.com/articles/journal_contribution/Biomimetic_Total_Synthesis_of_Doitunggarcinone_A_and_Garcibracteatone/2312809
10.1021/jo500027k.s004