%0 Journal Article %A Chun, Jiseul %A Kang, Sungah %A Park, Nojin %A Park, Eun Ji %A Jin, Xing %A Kim, Kwang-Dae %A Seo, Hyun Ook %A Lee, Sang Moon %A Kim, Hae Jin %A Kwon, Woo Hyun %A Park, Young-Kwon %A Kim, Ji Man %A Kim, Young Dok %A Son, Seung Uk %D 2014 %T Metal–Organic Framework@Microporous Organic Network: Hydrophobic Adsorbents with a Crystalline Inner Porosity %U https://acs.figshare.com/articles/journal_contribution/Metal_Organic_Framework_Microporous_Organic_Network_Hydrophobic_Adsorbents_with_a_Crystalline_Inner_Porosity/2296576 %R 10.1021/ja500362w.s001 %2 https://ndownloader.figshare.com/files/3934042 %K MON materials %K chemical etching %K MOF results %K Hydrophobic Adsorbents %K UiO %K microporous materials %K Crystalline Inner PorosityThis work reports %K MONs forms %X This work reports the synthesis and application of metal–organic framework (MOF)@microporous organic network (MON) hybrid materials. Coating a MOF, UiO-66-NH2, with MONs forms hybrid microporous materials with hydrophobic surfaces. The original UiO-66-NH2 shows good wettability in water. In comparison, the MOF@MON hybrid materials float on water and show excellent performance for adsorption of a model organic compound, toluene, in water. Chemical etching of the MOF results in the formation of hollow MON materials. %I ACS Publications