Rhodium(III)-Catalyzed Intermolecular Amidation with Azides via C(sp<sup>3</sup>)–H Functionalization Nuancheng Wang Renhe Li Liubo Li Shansheng Xu Haibin Song Baiquan Wang 10.1021/jo5008515.s002 https://acs.figshare.com/articles/dataset/Rhodium_III_Catalyzed_Intermolecular_Amidation_with_Azides_via_C_sp_sup_3_sup_H_Functionalization/2285455 The amidation reactions of 8-methylquinolines with azides catalyzed by a cationic rhodium­(III) complex proceed efficiently to give quinolin-8-ylmethanamine derivatives in good yields via C­(sp<sup>3</sup>)–H bond activation under external oxidant-free conditions. A catalytically competent five-membered rhodacycle has been isolated and characterized, revealing a key intermediate in the catalytic cycle. 2014-06-06 00:00:00 rhodacycle Azide quinolin Amidation azide Rhodium derivative rhodium FunctionalizationThe activation catalytically yield amidation methylquinoline cationic Intermolecular bond