Rhodium(III)-Catalyzed Intermolecular
Amidation with
Azides via C(sp<sup>3</sup>)–H Functionalization
Nuancheng Wang
Renhe Li
Liubo Li
Shansheng Xu
Haibin Song
Baiquan Wang
10.1021/jo5008515.s002
https://acs.figshare.com/articles/dataset/Rhodium_III_Catalyzed_Intermolecular_Amidation_with_Azides_via_C_sp_sup_3_sup_H_Functionalization/2285455
The amidation reactions of 8-methylquinolines
with azides catalyzed
by a cationic rhodium(III) complex proceed efficiently to give quinolin-8-ylmethanamine
derivatives in good yields via C(sp<sup>3</sup>)–H bond activation
under external oxidant-free conditions. A catalytically competent
five-membered rhodacycle has been isolated and characterized, revealing
a key intermediate in the catalytic cycle.
2014-06-06 00:00:00
rhodacycle
Azide
quinolin
Amidation
azide
Rhodium
derivative
rhodium
FunctionalizationThe
activation
catalytically
yield
amidation
methylquinoline
cationic
Intermolecular
bond