Agou, Tomohiro Wasano, Tatsuya Sasamori, Takahiro Tokitoh, Norihiro Syntheses and Structures of Stable 1‑Aminoalumole Derivatives Reaction of an isolable 1-bromoalumole with LiN­(SiMe<sub>3</sub>)<sub>2</sub> in toluene afforded a lithium 1,1-diaminodialumoluide, while in THF the corresponding 1-aminoalumole–THF complex was obtained. These amino-substituted alumole derivatives are characterized by X-ray crystallographic analysis and NMR spectroscopy. The lithium 1,1-diaminoalumoluide and the 1-aminoalumole–THF complex were converted to each other by ligand exchange reactions. Aminoalumole;Stable;Structures;ligand exchange reactions;LiN;Synthese;isolable;aminoalumole;derivative;lithium;diaminoalumoluide;DerivativesReaction;bromoalumole;THF;toluene;NMR spectroscopy;alumole;analysis;diaminodialumoluide 2014-12-08
    https://acs.figshare.com/articles/dataset/Syntheses_and_Structures_of_Stable_1_Aminoalumole_Derivatives/2227852
10.1021/om501055f.s002