%0 Generic
%A García-Rodríguez, Raúl
%A Simmonds, Hayley R.
%A Wright, Dominic S.
%D 2014
%T Formation of a Heterometallic AlIII/SmIII Complex Involving a Novel [EtAl(2-py)2O]2– Ligand (2-py = 2‑Pyridyl)
%U https://acs.figshare.com/articles/dataset/Formation_of_a_Heterometallic_Al_sup_III_sup_Sm_sup_III_sup_Complex_Involving_a_Novel_EtAl_2_py_sub_2_sub_O_sup_2_sup_Ligand_2_py_2_Pyridyl_/2223409
%R 10.1021/om5009132.s002
%2 https://ndownloader.figshare.com/files/3859336
%K novel multifunctional dianionic ligand
%K EtAl
%K formation
%K Sm
%K heterobimetallic sandwich compounds
%X Controlled
O2 oxidation of the Sm(II) sandwich compound
[{EtAl(2-py)3}2Sm] (1a) gives
the Sm(III)/Al(III) compound [{EtAl(2-py)3}{EtAl(2-py)2O}Sm]2 (2), containing the novel multifunctional
dianionic ligand [EtAl(2-py)2O]2–. The formation of an O-bridged Al-O-Sm arrangement in the structure
of 2 is potentially relevant to the catalytic epoxidation
of styrene with dry air using heterobimetallic sandwich compounds
like 1a.
%I ACS Publications