Facile Access to Novel [60]Fullerenyl Diethers and
[60]Fullerene–Sugar Conjugates via Annulation of Diol Moieties
Wen-Qiang Zhai
Sheng-Peng Jiang
Ru-Fang Peng
Bo Jin
Guan-Wu Wang
10.1021/acs.orglett.5b00536.s001
https://acs.figshare.com/articles/journal_contribution/Facile_Access_to_Novel_60_Fullerenyl_Diethers_and_60_Fullerene_Sugar_Conjugates_via_Annulation_of_Diol_Moieties/2175745
A general and facile annulation of
various diol motifs to [60]fullerene
has been developed. This protocol can afford not only 6- to 10-membered-ring
fullerenyl diethers in one step from simple acyclic diols but also
directly couple [60]fullerene with a variety of structurally diverse
sugars. The [60]fullerene-sugar conjugates formed do not require any
linker moiety and maintain their inherent structural integrity. The
electrochemistry of the fullerenyl diethers and [60]fullerene-sugar
conjugates has also been investigated.
2015-04-17 00:00:00
Annulation
Facile Access
conjugate
integrity
variety
annulation
fullerenyl diethers
Fullerene
Diol MoietiesA
diol motifs
Diether
couple
fullerene
linker moiety
Fullerenyl
acyclic diols
electrochemistry
Conjugate