TY - DATA T1 - Synthesis and Chemical Reactivity of Tetrahydro[60]fullerene Epoxides with Both Amino and Aryl Addends PY - 2015/04/17 AU - Sisi Liang AU - Liang Xu AU - Liangbing Gan UR - https://acs.figshare.com/articles/dataset/Synthesis_and_Chemical_Reactivity_of_Tetrahydro_60_fullerene_Epoxides_with_Both_Amino_and_Aryl_Addends/2175574 DO - 10.1021/acs.joc.5b00287.s002 L4 - https://ndownloader.figshare.com/files/3809500 KW - epoxide KW - aryl group KW - chemical reactivity KW - aryl addends exhibit KW - Chemical Reactivity KW - tetrahydro KW - diol derivatives N2 - Tetrahydro­[60]­fullerene epoxides C60(O)­Arn(NR2)4–n, n = 1, 2, have been prepared by treating 1,4-adducts C60(OH)­Ph and C60(Tol)2 with cyclic secondary amines. The epoxy moieties in these mixed tetrahydro[60]­fullerene epoxides were hydrolyzed into the corresponding diol derivatives, which were further oxidized into diketone open-cage fullerenes with a 10-membered orifice. A few other reactions also showed that the present tetrahydro[60]­fullerene epoxides with both amino and aryl addends exhibit improved chemical reactivity over the tetraamino[60]­fullerene epoxide without any aryl group. ER -