TY - DATA T1 - Asymmetric Dearomatization of Naphthols via a Rh-Catalyzed C(sp2)–H Functionalization/Annulation Reaction PY - 2015/04/22 AU - Jun Zheng AU - Shao-Bo Wang AU - Chao Zheng AU - Shu-Li You UR - https://acs.figshare.com/articles/dataset/Asymmetric_Dearomatization_of_Naphthols_via_a_Rh_Catalyzed_C_sp_sup_2_sup_H_Functionalization_Annulation_Reaction/2174257 DO - 10.1021/jacs.5b01707.s002 L4 - https://ndownloader.figshare.com/files/3808183 KW - enantioenriched spirocyclic enones KW - presence KW - Functionalization KW - stereogenic KW - enantioselective KW - quaternary KW - functionalization KW - Naphthol KW - yield KW - ReactionA KW - catalyst KW - oxidant KW - center KW - chiral KW - Asymmetric Dearomatization KW - dearomatization KW - alkyne KW - aryl KW - Cp KW - Cu N2 - A Rh-catalyzed enantioselective dearomatization of 1-aryl-2-naphthols with internal alkynes via C–H functionalization reaction was achieved. In the presence of a chiral Cp/Rh catalyst and combined oxidants of Cu­(OAc)2 and air (oxygen), various highly enantioenriched spirocyclic enones bearing an all-carbon quaternary stereogenic center could be synthesized in 33–98% yields with up to 97:3 er. ER -