Romero-Pérez, Sonia Camacho-García, Jorge Montoro-García, Carlos López-Pérez, Ana M. Sanz, Alfredo Mayoral, María José González-Rodríguez, David G‑Arylated Hydrogen-Bonded Cyclic Tetramer Assemblies with Remarkable Thermodynamic and Kinetic Stability The preparation and self-assembly of novel G–C dinucleoside monomers that are equipped with electron-poor aryl groups at the G-<i>N</i><sup>2</sup> amino group have been studied. Such monomers associate via Watson–Crick H-bonding into discrete unstrained tetrameric macrocycles that arise as a thermodynamically and kinetically stabilized product in a wide variety of experimental conditions, including very polar solvent environments and low concentrations. G-arylation produces an increased stability of the cyclic assembly, as a result of a subtle interplay between enthalpic and entropic effects involving the solvent coordination sphere. Kinetic StabilityThe preparation;stability;cyclic assembly;concentration;kinetically;dinucleoside;variety;unstrained tetrameric macrocycles;Watson;Tetramer;Cyclic;Assemblies;enthalpic;coordination sphere;Remarkable Thermodynamic;entropic effects;aryl;Such monomers;interplay 2015-06-05
    https://acs.figshare.com/articles/journal_contribution/G_Arylated_Hydrogen_Bonded_Cyclic_Tetramer_Assemblies_with_Remarkable_Thermodynamic_and_Kinetic_Stability/2161180
10.1021/acs.orglett.5b01042.s001