10.1021/acs.joc.5b00907.s001
Sunil
K. Sundalam
Sunil
K.
Sundalam
David R. Stuart
David R.
Stuart
Base Mediated Synthesis
of Alkyl-aryl Ethers from
the Reaction of Aliphatic Alcohols and Unsymmetric Diaryliodonium
Salts
American Chemical Society
2015
arylating
aspect
substrate scope
display
ether
utility
Unsymmetric Diaryliodonium SaltsThe base
sustainability
base Mediated Synthesis
aliphatic alcohol pronucleophiles
proceed
reagent
Aliphatic Alcohols
unsymmetric diaryliodonium salt electrophiles
Ether
2015-06-19 00:00:00
Journal contribution
https://acs.figshare.com/articles/journal_contribution/Base_Mediated_Synthesis_of_Alkyl_aryl_Ethers_from_the_Reaction_of_Aliphatic_Alcohols_and_Unsymmetric_Diaryliodonium_Salts/2156770
The
base mediated coupling of aliphatic alcohol pronucleophiles
with unsymmetric diaryliodonium salt electrophiles is described. This
metal-free reaction is operationally simple, proceeds at mild temperature,
and displays broad substrate scope to generate industrially important
alkyl-aryl ethers in moderate to excellent yield. The synthetic utility
of these reactions is demonstrated, and aspects of sustainability
are highlighted by the use of unsymmetric aryl(mesityl)iodonium arylating
reagents.