%0 Generic %A Chen, Yuxiang %A Cao, Wei %A Wang, Kang %A Jiang, Jianzhuang %D 2015 %T Unprecedented Phthalocyanines Bearing Eight Di-butylamino Peripheral Substituents: Synthesis, Spectroscopy, and Structure %U https://acs.figshare.com/articles/dataset/Unprecedented_Phthalocyanines_Bearing_Eight_Di_butylamino_Peripheral_Substituents_Synthesis_Spectroscopy_and_Structure/2120413 %R 10.1021/acs.inorgchem.5b01734.s002 %2 https://ndownloader.figshare.com/files/3754213 %K cyclic voltammetry %K electrochemistry %K Unprecedented Phthalocyanines Bearing %K basis %K absorption %K IR spectroscopy %K Substituent %K Synthesi %K octaki %K Mg %K StructureUnprecedented %K Spectroscopy %K compound %K Zn %K NMR %K spectroscopic methods %K 2 H %K spectra %K diffraction %K analysis %K novel phthalocyanine derivatives %K Cu %X Unprecedented 2,3,9,10,16,17,23,24-octakis­(di-butylamino)­phthalocyanine compounds M­{Pc­[N­(C4H9)2]8} (M = 2H, Mg, Cu, Zn) (14) were prepared and structurally characterized on the basis of single-crystal X-ray diffraction analysis, representing the first structurally characterized alkylamino-substituted phthalocyanine examples. These novel phthalocyanine derivatives have also been characterized by a wide range of spectroscopic methods including MALDI-TOF mass spectra, NMR, electronic absorption, and IR spectroscopy in addition to elemental analysis. Their electrochemistry was also studied by cyclic voltammetry. %I ACS Publications