Abe, Masaaki Yamada, Hiroaki Okawara, Toru Fujitsuka, Mamoru Majima, Tetsuro Hisaeda, Yoshio Covalently Attached Porphycene–Ferrocene Dyads: Synthesis, Redox-Switched Emission, and Observation of the Charge-Separated State Two new porphycenes functionalized with ferrocenyl pendants have been synthesized and characterized spectroscopically and structurally. The porphycene-based emission in porphycene–ferrocene dyads was switched on and off by the reversible control of the ferrocenyl pendant redox states. Transient absorption spectroscopy with a femtosecond laser-pulsed technique has successfully detected the picosecond charge-separated excited state of the dyad upon Q-band excitation of the porphycene ring. porphycenes functionalized;dyad;ferrocenyl pendants;Transient absorption spectroscopy;ferrocenyl pendant redox states;porphycene ring 2016-01-04
    https://acs.figshare.com/articles/journal_contribution/Covalently_Attached_Porphycene_Ferrocene_Dyads_Synthesis_Redox_Switched_Emission_and_Observation_of_the_Charge_Separated_State/2092321
10.1021/acs.inorgchem.5b02078.s001