TY - DATA T1 - A Cyclic Disilylated Stannylene: Synthesis, Dimerization, and Adduct Formation PY - 2015/12/16 AU - Henning Arp AU - Judith Baumgartner AU - Christoph Marschner AU - Thomas Mùˆller UR - https://acs.figshare.com/articles/dataset/A_Cyclic_Disilylated_Stannylene_Synthesis_Dimerization_and_Adduct_Formation/2015577 DO - 10.1021/ja1100883.s001 L4 - https://ndownloader.figshare.com/files/3586701 KW - adduct KW - Cyclic Disilylated Stannylene KW - donor molecules KW - Adduct FormationReaction KW - formation KW - endocyclic distannene KW - stannylene KW - PEt 3 N2 - Reaction of 1,4-dipotassio-1,1,4,4-tetrakis(trimethylsilyl)tetramethyltetrasilane with [(Me3Si)2N]2Sn led to the formation of an endocyclic distannene via the dimerization of a transient stannylene. In the presence of strong donor molecules such as PEt3, the stannylene could be trapped as adduct. Reaction of the PEt3 derivative with B(C6F5)3 gave rise to the formation of the stannylene B(C6F5)3 adduct. ER -