10.6084/m9.figshare.1621343.v1
Xiaofang Wang
Xiaofang
Wang
Feifei Yang
Feifei
Yang
Hong Zhang
Hong
Zhang
Yuhui Luo
Yuhui
Luo
Xiaoyang Yu
Xiaoyang
Yu
From 2D layer to 2D → 3D parallel interpenetration: Syntheses, structures and luminescent properties
Taylor & Francis Group
2015
2 D layer
structure determination
interpenetrating network
ir
1 manifests
coordination polymers
fluorescence properties
2015-12-08 20:31:45
Journal contribution
https://tandf.figshare.com/articles/journal_contribution/From_2D_layer_to_2D_8594_3D_parallel_interpenetration_Syntheses_structures_and_luminescent_properties/1621343
<div><p></p><p>Two new coordination polymers based on 1,1’-(1,4-butanediyl)bis(imidazole) (bbi) and 5-hydroxyisophthalic acid (OH-BDC), [Co<sub>2</sub>(HO-BDC)<sub>2</sub>(bbi)<sub>2</sub>]·H<sub>2</sub>O (<b>1</b>) and [Zn(HO-BDC)(bbi)] (<b>2</b>), have been hydrothermally synthesized. The complexes were characterized by single crystal X-ray diffraction, IR and elemental analysis. The structure determination reveals that <b>1</b> manifests a deeply corrugated 2D layer with a (4,4) lattice. For <b>2</b>, there is a highly undulating 2D (4,4) layer structure. The layers penetrate by each other to give a 2D → 3D parallel interpenetrating network. Fluorescence properties and thermal stabilities of <b>1</b> and <b>2</b> in the solid state have been studied.</p></div>