TY - DATA T1 - Tribromo Phloroglucinol as a Novel and Highly Efficient Reagent for the Conversion of Benzothioamides to the Corresponding 1,2,4-Thiadiazoles PY - 2015/06/10 AU - Hassan Zali-Boeini AU - Seyed Gholamhossein Mansouri UR - https://tandf.figshare.com/articles/journal_contribution/Tribromo_Phloroglucinol_as_a_Novel_and_Highly_Efficient_Reagent_for_the_Conversion_of_Benzothioamides_to_the_Corresponding_1_2_4_Thiadiazoles/1390512 DO - 10.6084/m9.figshare.1390512.v3 L4 - https://ndownloader.figshare.com/files/2034637 KW - conversion KW - 6 molar equivalents KW - Benzothioamide KW - Tribromo Phloroglucinol KW - TBTHB KW - dimethyl sulfoxide KW - hexahydroxybenzene KW - reagent KW - formation KW - diaryl KW - dmso KW - min KW - yield KW - Efficient Reagent KW - thiadiazole N2 - 2,4,6-Tribromo-1,3,5-trihydroxybenzene (TBTHB) as a reagent was efficiently reacted with 6 molar equivalents of benzothioamides in dimethyl sulfoxide (DMSO), and the corresponding 3,5-diaryl-1,2,4-thiadiazoles were obtained in almost quantitative yields (91–98%) and in short times (15–20 min) with the formation of hexahydroxybenzene as a rather valuable by-product. ER -