%0 Generic %A Li, Xiao-Ling %A Liu, Guang-Zhen %A Xin, Ling-Yun %A Li, Gui-Lian %D 2015 %T Synthesis, Crystal Structure, and Properties of Two 2D Lamella Coordination Polymers Generated from Unsymmetrically Carboxylate Bridging Ligand %U https://tandf.figshare.com/articles/dataset/Synthesis_Crystal_Structure_and_Properties_of_Two_2D_Lamella_Coordination_Polymers_Generated_from_Unsymmetrically_Carboxylate_Bridging_Ligand/1254928 %R 10.6084/m9.figshare.1254928.v2 %2 https://ndownloader.figshare.com/files/1810427 %2 https://ndownloader.figshare.com/files/1810428 %2 https://ndownloader.figshare.com/files/1810429 %2 https://ndownloader.figshare.com/files/1810430 %2 https://ndownloader.figshare.com/files/1810431 %K Magnetic measurements show %K crystal structure %K 1 manifests %K unsymmetrical ligand h 2epda %K transition metals %K 2 D lamella coordination polymers %K 2 D layer %K 2 D lamella Coordination Polymers Generated %K tg %K metamagnetic behaviors %K 2 exhibits %K bc plane %K H 2hmph acid %K unsymmetrical ligands %K 2 D lamella structure %X

Self-assembly between simple unsymmetrical ligands, such as h2epda (5-ethyl-pyridine-2,3-dcarboxylic acid) and H2hmph(homophthalic acid) and two transition metals produce two new 2D lamella coordination polymers [Cu(hedpa)2]n1 and [Co(hmph)(bpe)]n2 (bpe = 1,2-di(4-pyridyl)ethylene), respectively. The 2D lamella structure of 2 features hmph-bridged binuclear cobalt(II) chains joined by less flexible trans-bpe ligands, whereas the 2D layer of 1 manifests that unsymmetrical ligand h2epda directly bridges mononuclear copper(II) running along the bc plane. The thermogravimetric (TG) reveal that both compounds are stable. Magnetic measurements show that complex 2 exhibits global metamagnetic behaviors.

%I Taylor & Francis