%0 Journal Article %A Fang, Ming %A Wang, Tao %A Lu, Xulin %A Song, Aijun %A Shen, Li %A Tian, Hongyan %D 2014 %T Two 3-D metal organic frameworks containing 2,2′-bipyridine-5,5′-dicarboxylic acid: synthesis, structure, and magnetic properties %U https://tandf.figshare.com/articles/journal_contribution/Two_3_D_metal_organic_frameworks_containing_2_2_8242_bipyridine_5_5_8242_dicarboxylic_acid_synthesis_structure_and_magnetic_properties/1103234 %R 10.6084/m9.figshare.1103234.v4 %2 https://ndownloader.figshare.com/files/1592121 %K 2,2′-Bipyridine-5,5′-dicarboxylic anion %K Manganese %K Zinc %K MOFs %K Antiferromagnetic coupling %X

Two metal organic frameworks, {[M(H2BPDC)(SO4)]}n (M = Mn (1), Zn (2)); BPDC = 2,2′-bipyridine-5,5′-dicarboxylic anion), have been synthesized under hydrothermal conditions. The structure analyses of 1 and 2 reveal that the two compounds have similar 3-D structures. Compound 1 crystallizes in the orthorhombic system with space group Pnma, while 2 displays a monoclinic system with space group P21/n. Magnetic investigation suggests that weak antiferromagnetic coupling exists between adjacent Mn2+ ions in 1.

Two metal organic frameworks, {[M(H2BPDC)(SO4)]}n (M = Mn (1), Zn (2)); BPDC = 2,2'-bipyridine-5,5'-dicarboxylic anion), were synthesized and structurally characterized. Magnetic investigations suggest that weak antiferromagnetic coupling exists between adjacent Mn2+ centers.

%I Taylor & Francis