%0 Journal Article %A Sokolowska, Katarzyna %A Sicinski, Rafal R. %D 2014 %T Unusual Course of the Reaction of Allyl Phosphine Oxides with the Grundmann Ketone %U https://tandf.figshare.com/articles/journal_contribution/Unusual_Course_of_the_Reaction_of_Allyl_Phosphine_Oxides_with_the_Grundmann_Ketone/1057872 %R 10.6084/m9.figshare.1057872.v4 %2 https://ndownloader.figshare.com/files/1535521 %K allyl %K phosphine %K oxides %K grundmann %K ketone %X

This article describes efficient preparation of isomeric allyl phosphine oxides possessing a protected cyclohexanediol fragment. Their base-catalyzed interconversions are examined and reactions with the Grundmann ketone provide an adduct containing the rearranged vinyl phosphine oxide moiety, instead of 19-norvitamin D3 analogs, the expected products of the Horner–Wittig process.

%I Taylor & Francis