Time evolution of Im() for (a) <sup>87</sup>Rb, (b) <sup>23</sup>Na and (c)<sup>7</sup>Li Vineet Bharti Ajay Wasan 10.6084/m9.figshare.1011994.v1 https://iop.figshare.com/articles/figure/_Time_evolution_of_Im_span_class_inline_eqn_img_src_http_ej_iop_org_images_0953_4075_46_12_125501_Fu/1011994 <p><strong>Figure 6.</strong> Time evolution of Im() for (a) <sup>87</sup>Rb, (b) <sup>23</sup>Na and (c)<sup>7</sup>Li. The parameters used in these calculations are the same as in figure <a href="http://iopscience.iop.org/0953-4075/46/12/125501/article#jpb461983f5" target="_blank">5</a>. The green dash-dotted and black dotted curves are for the four-level system with and without the switching field, respectively. The red solid and blue dashed curves are for the six-level system with and without the switching field, respectively.</p> <p><strong>Abstract</strong></p> <p>We present a six-level atomic system using a density matrix approach to show variation of the optical properties in an -type Doppler-broadened system for the D2 line of alkali atoms with the nuclear spin <em>I</em> = 3/2, i.e. <sup>87</sup>Rb, <sup>23</sup>Na and <sup>7</sup>Li. The variation in optical properties arises due to the presence of multiple excited states with varying separations. These excited states cause asymmetry in absorption profiles. This asymmetric nature is more prominent for an atom with more closely spaced hyperfine levels in the excited state. In room temperature atomic vapour, the enhanced absorption at the line centre starts to disappear with a decrease in hyperfine separation. We also discuss the transient behaviour of considered atoms, which is in good agreement with an absorption profile in each case. This approach opens a possibility of realizing the optical switching application in a realistic atom.</p> 2013-06-10 00:00:00 profile 87 Rb variation 23 Na density matrix approach states cause asymmetry D 2 line separation absorption Atomic Physics Molecular Physics