Two 3-D CdII/ZnII complexes based on mixed 1,1-cyclobutanedicarboxylate and 4,4′-bipyridine ligands

Hu, Min; Peng, Dong-Lai; Zhao, Hui; Wang, Zhuo-Wei; Fang, Shao-Ming

doi:10.6084/m9.figshare.1378792.v3

gcoo_a_1038527_sm4153.doc (1.04 MB)

Two 3-D Cd^II/Zn^II complexes based on mixed 1,1-cyclobutanedicarboxylate and 4,4′-bipyridine ligands

Version 3 2015-05-27, 13:55

Version 2 2015-05-27, 13:55

Version 1 2015-05-27, 13:55

journal contribution

posted on 2015-05-27, 13:55 authored by Min Hu, Dong-Lai Peng, Hui Zhao, Zhuo-Wei Wang, Shao-Ming Fang

Two new 3-D complexes, [M(L)(4bpy)_0.5(H₂O)]_∞ [M = Cd (1) and = Zn (2)], based on mixed 1,1-cyclobutanedicarboxylic acid (H₂L) and 4,4′-bipyridine (4bpy) have been synthesized; 1 and 2 feature (3,4)-connected (6³)(6⁵.8) topological networks consisting of pillared 2-D [M(L)(H₂O)]_∞ layered motifs. Complexes 1 and 2 are photoluminescent materials.