Synthesis of Biphenyl-Based Ligand: Application in Copper-Mediated Chemoselective Michael Reaction

Sundar, M. Shyam; Bedekar, Ashutosh V.

doi:10.6084/m9.figshare.1162800.v4

lsyc_a_946996_sm1854.pdf (1.51 MB)

Synthesis of Biphenyl-Based Ligand: Application in Copper-Mediated Chemoselective Michael Reaction

Version 4 2014-10-21, 00:39

Version 3 2014-10-21, 00:39

Version 2 2014-10-17, 21:59

Version 1 2014-10-21, 00:39

journal contribution

posted on 2014-10-21, 00:39 authored by M. Shyam Sundar, Ashutosh V. Bedekar

A biphenyl-based ligand attached was synthesized and screened in copper-mediated Michael reaction. The catalyst system works well with carbon or sulfur nucleophiles as Michael donors and cyclohexenone or chalcones as the acceptors under mild and neutral reaction conditions in a chemoselective manner.